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A low-spin Fe(iii) complex with 100-ps ligand-to-metal charge transfer photoluminescence

Transition-metal complexes are used as photosensitizers1, in light-emitting diodes, for biosensing and in photocatalysis2. A key feature in these applications is excitation from the ground state to a charge-transfer state3,4; the long charge-transfer-state lifetimes typical for complexes of ruthenium5 and other precious metals are often essential to ensure high performance. There is much interest

Time-Resolved Laser Spectroscopy in Molecular Devices for Solar Energy Conversion

A complete characterization of solar energy conversion devices and the processes underlying their function is a challenge, and require a multitude of different experimental methods. This chapter discusses investigations of molecular solar cells and solar fuels devices by time-resolved laser spectroscopic methods. These methods have established important concepts we now use for understanding the fu

Contextualizing the quality of primary education in urban and rural settings : The case of Iringa Region, Tanzania

The purpose of the article is to discuss the term ‘quality’ in relation to primary education in Tanzania, and to contextualize quality and identify the premises for obtaining quality in primary school education in rural and urban settings. To understand opinions about the quality of education and the current situation in primary schools, the author conducted interviews with teachers and focus grou

Breit and QED effects on the 3d9 D3/2 2 →2D5/2 transition energy in Co-like ions

The multiconfiguration Dirac-Hartree-Fock theory is used to calculate the 3d9D3/22→2D5/2 transition energy for Co-like ions with Z=28-100. We investigate how electron correlation, frequency-independent and -dependent Breit interactions, as well as QED corrections vary along the sequence. The well-understood frequency-independent Breit contribution has the largest contribution for all ions. Among t

Nutrient control to prevent the occurrence of cyanobacterial blooms in a eutrophic lake in Southern Sweden, used for drinking water supply

Control of nutrients, mainly nitrogen (N) and phosphorus (P), plays a significant role in preventing cyanobacterial blooms (harmful algal blooms (HABs)). This study aims at evaluating changes in the risk of the occurrence of cyanobacterial blooms and advancing the understanding of how nitrogen and phosphorus affect the growth of cyanobacteria in a eutrophic lake, Lake Vombsjön, in southern Sweden.

Structural abnormalities detected by knee magnetic resonance imaging are common in middle-aged subjects with and without risk factors for osteoarthritis

Background and purpose — Few data are available regarding structural changes present in knees without radiographically evident osteoarthritis (OA). We evaluated the prevalence of findings suggestive of knee OA by magnetic resonance imaging (MRI) in middle-aged subjects without radiographic OA with or without OA risk factors. Patients and methods — 340 subjects from the Osteoarthritis Initiative, a

Preferred posture in lying and its association with scoliosis and windswept hips in adults with cerebral palsy

Objective: The aim of this study was to clarify the association of scoliosis and windswept hips with immobility, lying position, and time in lying, in adults with cerebral palsy (CP). Methods: This cross-sectional study included 830 adults (469 males and 361 females) with a diagnosis of CP, 16–73 years, and classified at levels I–V according to the Gross Motor Function Classification System (GMFCS

Occupational balance among family members of people in palliative care

Background: Today people can live a long time with a chronic cancer diagnosis, and it affects the entire family. Family members to patients in palliative care often have to leave valued occupations due to lack of time and energy, while new roles are forced upon them, potentially affecting their health. Objective: To explore occupational balance, needs and roles among family members to persons in p

The transnational dynamics of local remembrance : The Jewish past in a former shtetl in Poland

This article presents an example of how the transnational production of memory is at work in a small Polish town that, prior to the Holocaust, was a “shtetl.” The author uses transnational optics to take an in-depth look at how local memories of Jews and the Holocaust are formed in this particular locality and discusses the effects of transnational mnemonic encounters. She highlights the multiscal

Tracking the prograde P–T path of Precambrian eclogite using Ti-in-quartz and Zr-in-rutile geothermobarometry

A Fe–Ti-rich garnet, clinopyroxene, and quartz eclogite sample from the 1.0 Ga Sveconorwegian orogen, SW Sweden, contains abundant quartz, rutile, and zircon in distinct micro-textural sites: garnet core, garnet rim, and matrix, constituting an ideal case for investigation of the behavior of Zr-in-rutile and Ti-in-quartz at high-pressure and temperature. A P–T path, peaking at 16.5–19 kbar and 850

Impact of Thyroid Autoimmunity on Thyroid Function in 12-year-old Children with Celiac Disease

Objectives: Celiac disease (CD) is associated with thyroid autoimmunity and other autoimmune diseases. Data are, however, lacking regarding the relationship between thyroid autoimmunity and thyroid function, especially in regard to CD. Our aim was to investigate the impact of thyroid autoimmunity on thyroid function in 12-year-old children with CD compared to their healthy peers. Methods: A case-r

A physics-based micromechanical model for electroactive viscoelastic polymers

Electroactive polymers with time-dependent behavior are considered in the present paper by way of a new physics-based micromechanical model; such viscoelastic response is described by the internal evolution of the polymer network, providing a new viewpoint on the stress relaxation occurring in elastomers. The main peculiarity of such internally rearranging materials is their capacity to locally re

Association between QTc prolongation and mortality in patients with suspected poisoning in the emergency department : A transnational propensity score matched cohort study

Objectives Poisoning is a frequent cause of admission to the emergency department (ED) and may involve drugs known to prolong the QT interval. This study aims to describe the prevalence of QTc prolongation among ED patients with suspected poisoning and to calculate the absolute and relative risk of mortality or cardiac arrest associated with a prolonged QTc interval. Methods We performed a registe

How bacteria hack the matrix and dodge the bullets of immunity

Haemophilus influenzae, Moraxella catarrhalis and Pseudomonas aeruginosa are common Gram-negative pathogens associated with an array of pulmonary diseases. All three species have multiple adhesins in their outer membrane, i.e. surface structures that confer the ability to bind to surrounding cells, proteins or tissues. This mini-review focuses on proteins with high affinity for the components of t

Optimal work extraction from quantum states by photo-assisted Cooper pair tunneling

The theory of quantum thermodynamics predicts fundamental bounds on work extraction from quantum states. As these bounds are derived in a very general and abstract setting, it is unclear how relevant they are in an experimental context, where control is typically limited. Here we address this question by showing that optimal work extraction is possible for a realistic engine. The latter consists o

Extensor-Coding

We devise an algorithm that approximately computes the number of paths of length k in a given directed graph with n vertices up to a multiplicative error of 1 ± . Our algorithm runs in time −24k(n + m) poly(k). The algorithm is based on associating with each vertex an element in the exterior (or, Grassmann) algebra, called an extensor, and then performing computations in this algebra. This connect

Escalation of commitment as an antecedent to noncompliance with information security policy

Purpose: This study aims to identify antecedents to noncompliance behavior influenced by decision contexts where investments in time, effort and resources are devoted to a task – referred to as a task unlikely to be completed without violating the organization’s information security policy (ISP). Design/methodology/approach: An empirical test of the suggested relationships in the proposed model wa

Underwater terrain navigation during realistic scenarios

Many ships today rely on Global Navigation Satellite Systems (GNSS), for their navigation, where GPS (Global Positioning System) is the most well-known. Unfortunately, the GNSS systems make the ships dependent on external systems, which can be malfunctioning, be jammed or be spoofed. There is today some proposed techniques where, e.g., bottom depth measurements are compared with known maps using B